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Physics of Metals and Metallography

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01.11.2023 | ELECTRICAL AND MAGNETIC PROPERTIES

Magnetocaloric Effect in La(Fe,Mn,Si)₁₃H_x Based Composites: Experiment and Theory

verfasst von: A. P. Kamantsev, A. A. Amirov, D. M. Yusupov, A. V. Golovchan, O. E. Kovalev, A. S. Komlev, A. M. Aliev

Erschienen in: Physics of Metals and Metallography | Ausgabe 11/2023

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Abstract

Samples of composites with different porosity and surface roughness based on LaFe_11.4Mn_0.3Si_1.3H_1.6 (LFMSH) alloy powders were obtained, their magnetocaloric properties were studied by the direct method in cyclic magnetic fields of μ₀H = 1.2 T with a frequency of 2 Hz. The maximal value of the adiabatic temperature change in pure LFMSH powder was ΔT = 3 K at T₀ = 287 K in the sample cooling regime, and for composite samples, this value was approximately two times lower than that in the powder. The effect of Mn and H atoms on the electronic structure and local magnetic characteristics of the initial La(Fe,Si)₁₃ alloy was studied using electron density functional theory. Replacement of some Fe atoms with Mn reduces the total magnetic moment and somewhat lowers the Curie temperature. In contrast, hydrogenation leads to an increase in exchange interactions between Fe atoms located at the vertices of the icosahedron and an increase in the Curie temperature.

Vorheriger Artikel Magnetocaloric Effect and Phase Separation: Theory and Prospects

Nächster Artikel Magnetocaloric Effect of RCo5 (with R = Gd, Tb, Dy, and Ho) Alloys

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Titel: Magnetocaloric Effect in La(Fe,Mn,Si)13Hx Based Composites: Experiment and Theory
verfasst von: A. P. Kamantsev
A. A. Amirov
D. M. Yusupov
A. V. Golovchan
O. E. Kovalev
A. S. Komlev
A. M. Aliev
Publikationsdatum: 01.11.2023
Verlag: Pleiades Publishing
Erschienen in: Physics of Metals and Metallography / Ausgabe 11/2023
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI: https://doi.org/10.1134/S0031918X23601695

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