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Wood Science and Technology

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30.08.2022 | Original

Dissolution and degradation of cellulosic fiber in carboxylic acid choline chloride-based deep eutectic solvents

verfasst von: Xinping Wang, Xingmei Lu, Honghui Zhao, Changmei Lin, Liufang Ni, Shilin Cao, Xiaojuan Ma

Erschienen in: Wood Science and Technology | Ausgabe 5/2022

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Abstract

In this study, bleached chemical pulp from hardwood was treated with different carboxylic acid choline chloride-based deep eutectic solvents (CA/ChCl DESs) including formic acid, acetic acid, ethanedioic acid, propanedioic acid and choline chloride. The dissolution and degradation of cellulose and hemicellulose in chemical pulps in these DESs were analyzed, while the relationships between the polarity parameters of DESs and the degradation and dissolution of cellulosic fibers were discussed. The results show that dicarboxylic acids/ChCl were more conducive to the solubility and degradation of cellulosic fibers compared to monocarboxylic acids/ChCl at a higher temperature. In addition, the increase in alkyl of the CA could reduce the solubility to cellulosic fiber. The further study reveals that the dissolution and degradation of cellulosic fibers are generally governed both by temperature and the ability of DESs hydrogen bond acidity (α), while temperature shows little effect on α. However, no remarkable relationships were found between the DESs hydrogen bond basicity (β) and cellulose degradation and dissolution.

Vorheriger Artikel Chemical characterization of cherry (Prunus avium) extract in comparison with commercial mimosa and chestnut tannins

Nächster Artikel Building bridging structures and crystallization reinforcement in sodium silicate-modified poplar by dimethylol dihydroxyethylene urea

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Titel: Dissolution and degradation of cellulosic fiber in carboxylic acid choline chloride-based deep eutectic solvents
verfasst von: Xinping Wang
Xingmei Lu
Honghui Zhao
Changmei Lin
Liufang Ni
Shilin Cao
Xiaojuan Ma
Publikationsdatum: 30.08.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Wood Science and Technology / Ausgabe 5/2022
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI: https://doi.org/10.1007/s00226-022-01406-w

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